SDS_AQUAFIN-TC125_101023.pdf
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<h1>SDS_AQUAFIN-TC125_101023.pdf</h1> <p>Safety Data Sheet (SDS)</p> <p>Page 1/9</p> <p>OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.</p> <p>Printing date 10/10/2023</p> <p>Reviewed on 10/10/2023</p> <p>SECTION 1) CHEMICAL PRODUCT AND SUPPLIER'S IDENTIFICATION</p> <p>IDENTITY:</p> <p>Product Name: AQUAFIN-TC125 <br />Product Use Description:</p> <p>AQUAFIN, INC. <br />505 BLUE BALL RD. #160 <br />ELKTON, MD 21921</p> <p>Aromatic Polyurethane Elastomeric Waterproof Intermediate Coat, For Further Information, <br />Refer to the Product Technical Data Sheet.</p> <p>info@aquafin.net</p> <p>24 hr Emergency Phone: Chem-Tel (800) 255-3924 <br />Information Phone No: (410) 392-2300</p> <p>www.aquafin.net</p> <p>SECTION 2) HAZARDS IDENTIFICATION <br />Classification: <br />Aspiration Hazard - Category 1 <br />Skin Irritation - Category 3 <br />Eye Irritation - Category 2A <br />Respiratory Sensitizer (Solid/Liquid) - Category 1 <br />Skin Sensitizer - Category 1 <br />Germ Cell Mutagenicity - Category 1B <br />Carcinogenicity - Category 1B <br />Flammable Liquids Category 3</p> <p>Pictograms:</p> <p>Signal Word: <br />Danger</p> <p>Hazardous Statements - Physical: <br />H226 - Flammable liquid and vapor</p> <p>Hazardous Statements - Health: <br />H304 - May be fatal if swallowed and enters airways <br />H350 - May cause cancer (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard) <br />H319 - Causes serious eye irritation <br />H340 - May cause genetic defects (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard) <br />H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled <br />H316 - Causes mild skin irritation <br />H317 - May cause an allergic skin reaction</p> <p>Precautionary Statements - General: <br />P101 - If medical advice is needed, have product container or label at hand. <br />P102 - Keep out of reach of children.</p> <p>SDS AQUAFIN-TC125 <br />SDS DATE: 10-OCT-23</p> <p>Page 1 of 9</p> <p>P103 - Read label before use.</p> <p>Precautionary Statements - Prevention: <br />P201 - Obtain special instructions before use. <br />P202 - Do not handle until all safety precautions have been read and understood. <br />P280 - Wear protective gloves/protective clothing/eye protection/face protection. <br />P264 - Wash thoroughly after handling. <br />P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. <br />P233 - Keep container tightly closed. <br />P240 - Ground/bond container and receiving equipment. <br />P241 - Use explosion-proof [electrical/ventilating/lighting/...] equipment. <br />P242 - Use only non-sparking tools. <br />P243 - Take action to prevent static discharges. <br />P261 - Avoid breathing dust/fume/gas/mist/vapors/spray. <br />P284 - [In case of inadequate ventilation] wear respiratory protection. <br />P272 - Contaminated work clothing should not be allowed out of the workplace.</p> <p>Precautionary Statements - Response: <br />P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor. <br />P331 - Do NOT induce vomiting. <br />P308 + P313 - IF exposed or concerned: Get medical advice/attention. <br />P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue <br />rinsing. <br />P337 + P313 - If eye irritation persists: Get medical advice/attention. <br />P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. <br />P370 + P378 - In case of fire: Check Section-5 (Fire Fighting Measures) <br />P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. <br />P342 + P311 - If experiencing respiratory symptoms: Call a POISON CENTER/doctor. <br />P332 + P313 - If skin irritation occurs: Get medical advice/attention. <br />P302 + P352 - IF ON SKIN: Wash with plenty of water. <br />P333 + P313 - If skin irritation or a rash occurs: Get medical advice/attention. <br />P321 - Specific treatment (see section 4 on this SDS). <br />P362 + P364 - Take off contaminated clothing. And wash it before reuse.</p> <p>Precautionary Statements - Storage: <br />P405 - Store locked up. <br />P403 + P235 - Store in a well-ventilated place. Keep cool.</p> <p>Precautionary Statements - Disposal: <br />P501 - Dispose of contents/ container to an approved waste disposal plant.</p> <p>SECTION 3) COMPOSITION / INFORMATION ON INGREDIENTS <br />CAS</p> <p>Chemical Name</p> <p>0009040-80-6</p> <p>POLYURETHANE PREPOLYMER</p> <p>40% - 75%</p> <p>0064742-95-6</p> <p>AROMATIC HYDROCARBON MIXTURE >C9</p> <p>13% - 24%</p> <p>0013463-67-7</p> <p>TITANIUM DIOXIDE</p> <p>10% - 19%</p> <p>0001333-86-4</p> <p>CARBON BLACK</p> <p>0000091-08-7</p> <p>TOLUENE-2,6-DIISOCYANATE</p> <p>0.1% - 0.2%</p> <p>0000584-84-9</p> <p>2,4-TOLUENE DIISOCYANATE</p> <p>0.1% - 0.2%</p> <p>% by Weight</p> <p>4% - 7%</p> <p>SECTION 4) FIRST-AID MEASURES</p> <p>SDS AQUAFIN-TC125 <br />SDS DATE: 10-OCT-23</p> <p>Page 2 of 9</p> <p>Inhalation: <br />Remove source of exposure or move person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms: Call a <br />POISON CENTER/doctor. If breathing is difficult, trained personnel should administer emergency oxygen if advised to do so by the <br />POISON CENTER/doctor. <br />If exposed/feel unwell/concerned: Call a POISON CENTER/doctor.</p> <p>Skin Contact: <br />Take off contaminated clothing, shoes and leather goods (e.g. watchbands, belts). Gently blot or brush away excess product. Wash with <br />plenty of lukewarm, gently flowing water for a duration of 15-20 minutes. If skin irritation or rash occurs: Get medical advice/attention. Wash <br />contaminated clothing before re-use or discard. <br />IF exposed or concerned: Get medical advice/attention.</p> <p>Eye Contact: <br />Remove source of exposure or move person to fresh air. Rinse eyes cautiously with lukewarm, gently flowing water for several minutes, <br />while holding the eyelids open. Remove contact lenses, if present and easy to do. Continue rinsing for a duration of 15-20 minutes. Take <br />care not to rinse contaminated water into the unaffected eye or onto the face. If eye irritation persists: Get medical advice/attention. <br />Avoid direct contact. Wear chemical protective gloves, if necessary.</p> <p>Ingestion: <br />Immediately call a POISON CENTER/doctor. Do NOT induce vomiting. If vomiting occurs naturally, lie on your side, in the recovery <br />position. <br />Give 1 or 2 glasses of milk or water to drink and refer person to medical personnel. Do not give anything by mouth to an unconscious <br />person. <br />IF exposed or concerned: Get medical advice/attention.</p> <p>SECTION 5) FIRE-FIGHTING MEASURES <br />Suitable Extinguishing Media: <br />Dry chemical, foam, carbon dioxide water spray or fog is recommended. Water spray is recommended to cool or protect exposed materials <br />or structures. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous use of <br />foam and water on the same surface is to be avoided as water destroys the foam. Sand or earth may be used for small fires only.</p> <p>Unsuitable Extinguishing Media: <br />If water is used, use very large quantities of cold water. The reaction between water and hot isocyanate may be vigorous. <br />Water and foam may cause violent frothing and possibly endanger the life of the fire fighter.</p> <p>Specific Hazards in Case of Fire: <br />Water contamination will produce carbon dioxide. Do not reseal contaminated containers as pressure buildup may rupture them. <br />Excessive pressure or temperature may cause explosive rupture of containers. <br />Exposure to vapors of heated isocyanates can be extremely dangerous.</p> <p>Fire-fighting Procedures: <br />Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged <br />containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to <br />protect personnel. Water may be ineffective but can be used to cool containers exposed to heat or flame. Caution should be exercised <br />when using water or foam as frothing may occur, especially if sprayed into containers of hot, burning liquid. <br />Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.</p> <p>Special Protective Actions: <br />Wear NIOSH approved self-contained breathing apparatus in positive pressure mode with full-face piece. Boots, gloves (neoprene), <br />googles, and full protective clothing are also required. <br />Care should always be exercised in dust/mist areas.</p> <p>SECTION 6) ACCIDENTAL RELEASE MEASURES <br />Emergency Procedure: <br />Keep unnecessary people away; isolate hazard area and deny entry. Do not touch or walk through spilled material. Clean up immediately. <br />ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).</p> <p>Recommended Equipment: <br />Positive pressure, full-face piece self-contained breathing apparatus(SCBA), or positive pressure supplied air respirator with escape SCBA <br />(NIOSH approved).</p> <p>Personal Precautions:</p> <p>SDS AQUAFIN-TC125 <br />SDS DATE: 10-OCT-23</p> <p>Page 3 of 9</p> <p>Avoid breathing vapors. Avoid contact with skin, eyes or clothing. Do not touch damaged containers or spilled materials unless wearing <br />appropriate protective clothing.</p> <p>Environmental Precautions: <br />Stop spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems <br />and natural waterways by using sand, earth, or other appropriate barriers.</p> <p>Methods and Materials for Containment and Cleaning up: <br />Soak up material with absorbent and shovel into a chemical waste container. Cover container, but do not seal, and remove from work area. <br />Prepare a decontamination solution of 2.0% liquid detergent and 3-8% concentrated ammonium hydroxide in water (5-10% sodium <br />carbonate may be substituted for the ammonium hydroxide). Follow the precautions on the supplier's safety data sheets. All operations <br />should be performed by trained personnel familiar with the hazards of the chemicals used. Treat the spill area with the decontamination <br />solution, using about 10 parts of solution for each part of the spill, and allow it to react for at least 15 minutes. Carbon dioxide will be <br />evolved, leaving insoluble polyureas. Residues from spill cleanup, even when treated as described may continue to be regulated under <br />provisions or RCRA and require storage and disposal as hazardous waste. For major spills, call CHEMTREC (Chemical Transportation <br />Emergency Center) at 800-424-9300. <br />Slowly stir the isocyanate waste into the decontamination solution described above. Let stand for 48 hours, allowing the evolved carbon <br />dioxide to vent away, residues may still be subject to RCRA storage and disposal requirements.</p> <p>SECTION 7) HANDLING AND STORAGE <br />General: <br />Wash hands after use. <br />Do not get in eyes, on skin or on clothing. <br />Do not breathe vapors or mists. <br />Use good personal hygiene practices. <br />Eating, drinking and smoking in work areas is prohibited. <br />Remove contaminated clothing and protective equipment before entering eating areas. <br />Eyewash stations and showers should be available in areas where this material is used and stored. <br />Employee education and training in safe handling of this material is required under OSHA hazard communication standard. Individuals with <br />existing respiratory disease such as chronic bronchitis, emphysema, or asthma should not be exposed to isocyanates.</p> <p>Ventilation Requirements: <br />Use only with adequate ventilation to control air contaminants to their exposure limits. The use of local ventilation is recommended to <br />control emissions near the source. <br />Air circulation and exhaustion of isocyanate vapors must be maintained until the coatings have fully cured to insure that no potential health <br />hazard remains. Air circulation and exhaustion of isocyanate vapors must be maintained until the coatings have fully cured to insure that <br />no potential health hazard remains. <br />Exposure to vapors of heated isocyanates can be extremely dangerous.</p> <p>Storage Room Requirements: <br />Keep container(s) tightly closed and properly labeled. Store in cool, dry, well-ventilated areas away from heat, direct sunlight, strong <br />oxidizers and any incompatibilities. Store in approved containers and protect against physical damage. Keep containers securely sealed <br />when not in use. Indoor storage should meet OSHA standards and appropriate fire codes. Containers that have been opened must be <br />carefully resealed to prevent leakage. Empty container retain residue and may be dangerous. <br />Use non-sparking ventilation systems, approved explosion-proof equipment and intrinsically safe electrical systems in areas where this <br />product is used and stored.</p> <p>SECTION 8) EXPOSURE CONTROLS/PERSONAL PROTECTION <br />Eye Protection: <br />Wear eye protection with side shields or goggles. Wear indirect-vent, impact and splash resistant goggles when working with liquids. If <br />additional protection is needed for entire face, use in combination with a face shield.</p> <p>Skin Protection: <br />Use of gloves approved to relevant standards made from the following materials may provide suitable chemical protection: PVC, neoprene <br />or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical <br />resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. <br />Use of an apron and over- boots of chemically impervious materials such as neoprene or nitrile rubber is recommended to avoid skin <br />sensitization. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at <br />the specific workplace. Launder soiled clothes or properly disposed of contaminated material, which cannot be decontaminated.</p> <p>Respiratory Protection: <br />If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker, a respiratory protection <br />program that meets or is equivalent to OSHA 29 CFR 1910.134 and ANSI Z88.2 should be followed. Check with respiratory protective <br />equipment suppliers. <br />When airborne concentrations exceed or are expected to exceed the TLV, use MSHA/NIOSH approved positive pressure supplied air <br />respirator with a full-face piece or an air supplied hood. For emergencies, use a positive pressure self-container breathing apparatus. <br />Air purifying (cartridge type) respirators are not approved for protection against isocyanates.</p> <p>Appropriate Engineering Controls:</p> <p>SDS AQUAFIN-TC125 <br />SDS DATE: 10-OCT-23</p> <p>Page 4 of 9</p> <p>Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold <br />limit value.</p> <p>Chemical Name</p> <p>OSHA <br />TWA <br />(ppm)</p> <p>2,4-TOLUENE <br />DIISOCYANATE</p> <p>OSHA <br />TWA <br />(mg/m3)</p> <p>OSHA <br />STEL <br />(ppm)</p> <p>OSHA <br />STEL <br />(mg/m3)</p> <p>OSHATablesZ1,2,3</p> <p>0.02 ceiling 0.14 ceiling</p> <p>AROMATIC <br />HYDROCARBON <br />MIXTURE >C9</p> <p>500</p> <p>1</p> <p>2000</p> <p>1</p> <p>CARBON BLACK</p> <p>3.5</p> <p>1</p> <p>TITANIUM DIOXIDE</p> <p>15</p> <p>1</p> <p>TOLUENE-2,6DIISOCYANATE</p> <p>5</p> <p>1</p> <p>Chemical Name</p> <p>ACGIH <br />TWA <br />(ppm)</p> <p>2,4-TOLUENE <br />DIISOCYANATE</p> <p>0.005</p> <p>ACGIH <br />TWA <br />(mg/m3)</p> <p>OSHA <br />NIOSH <br />OSHA <br />Skin <br />TWA <br />Carcinogen designation <br />(ppm)</p> <p>ACGIH <br />STEL <br />(ppm)</p> <p>NIOSH <br />TWA <br />(mg/m3)</p> <p>a</p> <p>NIOSH <br />STEL <br />(mg/m3)</p> <p>NIOSH <br />Carcinogen <br />1</p> <p>3.5a <br />b</p> <p>NIOSH <br />STEL <br />(ppm)</p> <p>1 <br />1</p> <p>1</p> <p>ACGIH <br />STEL <br />(mg/m3)</p> <p>0.02</p> <p>AROMATIC <br />HYDROCARBON <br />MIXTURE >C9 <br />CARBON BLACK</p> <p>3 (I)</p> <p>TITANIUM DIOXIDE</p> <p>10</p> <p>TOLUENE-2,6DIISOCYANATE</p> <p>0.005</p> <p>0.02</p> <p>SECTION 9) PHYSICAL AND CHEMICAL PROPERTIES</p> <p>Physical and Chemical Properties <br />Density</p> <p>9.34 lb/gal</p> <p>Specific Gravity</p> <p>1.12</p> <p>VOC Regulatory</p> <p>2.07 lb/gal</p> <p>Appearance</p> <p>Pigmented Liquid</p> <p>Odor Threshold</p> <p>N.A.</p> <p>Odor Description</p> <p>Mild Aromatic</p> <p>pH</p> <p>N.A.</p> <p>Water Solubility</p> <p>Reacts with Water</p> <p>Flammability</p> <p>N/A</p> <p>Flash Point Symbol</p> <p>N.A.</p> <p>Flash Point</p> <p>58 °C</p> <p>Viscosity</p> <p>N.A.</p> <p>Lower Explosion Level</p> <p>N.A.</p> <p>Upper Explosion Level</p> <p>N.A.</p> <p>Vapor Pressure</p> <p>N.A.</p> <p>Vapor Density</p> <p>N.A.</p> <p>Freezing Point</p> <p>N.A.</p> <p>Melting Point</p> <p>N.A.</p> <p>Low Boiling Point</p> <p>163 °C</p> <p>High Boiling Point</p> <p>N.A.</p> <p>Auto Ignition Temp</p> <p>N.A.</p> <p>Decomposition Pt</p> <p>N.A.</p> <p>SDS AQUAFIN-TC125 <br />SDS DATE: 10-OCT-23</p> <p>Page 5 of 9</p> <p>Evaporation Rate</p> <p>N.A.</p> <p>Coefficient Water/Oil</p> <p>N.A.</p> <p>SECTION 10) STABILITY AND REACTIVITY <br />Stability: <br />Material is stable at standard temperature and pressure.</p> <p>Conditions to Avoid: <br />Heat, high temperature, open flame, sparks, and moisture. Contact with incompatible materials in a closed system will cause liberation of <br />carbon dioxide and buildup of pressure.</p> <p>Hazardous Reactions/Polymerization: <br />Will not occur under normal conditions but under high temperatures in the presence of alkalis,tertiary amines, and metal compounds will <br />accelerate polymerization. Possible evolution of carbon dioxide gas may rupture closed containers.</p> <p>Incompatible Materials: <br />This product will react with any material containing active hydrogens, such as water, alcohol, ammonia, amines, alkalis and acids, the <br />reaction with water is slow under 50°C, but is accelerated at higher temperature and in the presence of alkalis, tertiary amines, and metal <br />compounds. Some reactions can be violent. Material can react with strong oxidizing agents.</p> <p>Hazardous Decomposition Products: <br />Carbon dioxide, carbon monoxide, nitrogen oxides, trace amounts of hydrogen cyanide and unidentified organic compounds may be <br />formed during combustion.</p> <p>SECTION 11) TOXICOLOGICAL INFORMATION <br />Skin Corrosion/Irritation: <br />Isocyanates react with skin protein and moisture and can cause irritation. Prolonged contact can cause reddening, swelling, rash, scaling, <br />blistering, and, in some cases, skin sensitization. Individuals who have developed a skin sensitization can <br />develop these symptoms as a result of contact with very small amounts of liquid material or as a result of exposure to vapor. <br />Causes mild skin irritation</p> <p>Serious Eye Damage/Irritation: <br />Liquid, aerosols or vapors are severely irritating and can cause pain, tearing, reddening and swelling. Prolonged vapor contact may cause <br />conjunctivitis. Any level of contact should not be left untreated. <br />Causes serious eye irritation</p> <p>Respiratory/Skin Sensitization: <br />This product can produce asthmatic sensitization upon either single inhalation exposure to a relatively high concentration or upon repeated <br />inhalation exposure to lower concentrations. <br />May cause allergy or asthma symptoms or breathing difficulties if inhaled <br />May cause an allergic skin reaction</p> <p>Carcinogenicity: <br />May cause cancer (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)</p> <p>Germ Cell Mutagenicity: <br />May cause genetic defects (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)</p> <p>Reproductive Toxicity: <br />No data available</p> <p>Specific Target Organ Toxicity - Single Exposure: <br />No data available</p> <p>Specific Target Organ Toxicity - Repeated Exposure: <br />No data available</p> <p>Aspiration Hazard: <br />May be fatal if swallowed and enters airways</p> <p>Acute Toxicity: <br />Ingestion: Can result in irritating and corrosive action in the mouth, stomach tissue and digestive tract. Symptoms can include sore <br />throat, abdominal pain, nausea, vomiting and diarrhea. Small amounts of this product aspirated into the respiratory system during ingestion <br />or vomiting may cause mild to severe pulmonary injury.</p> <p>SDS AQUAFIN-TC125 <br />SDS DATE: 10-OCT-23</p> <p>Page 6 of 9</p> <p>ACUTE: Exposure may cause mucous membrane and respiratory tract irritation, tightness of chest, headache, shortness of breath, and a <br />dry cough. At concentrations exceeding current occupational limits and for sensitized individuals at levels less than or greater than current <br />occupational limits, asthma-like symptoms may occur. These symptoms may include coughing, wheezing, and shortness of breath. A <br />hypersensitive pneumonitis may also occur if the person is sensitized. This syndrome is characterized by fever, nonproductive cough, <br />wheezing, chills, and shortness of breath. Dizziness, anesthesia, drowsiness, unconsciousness and other central nervous system effects <br />may also result. The effects of acute exposure may be delayed in onset up to 12-24 hours. <br />CHRONIC: Repeated exposure above current occupational limits may cause an allergic sensitization of the respiratory <br />tract. This is characterized by an asthma-like response upon re-exposure to the chemical. The symptoms may include coughing, wheezing, <br />shortness of breath and chest tightness. Central nervous system (CNS) impairment possibly leading to unconsciousness.</p> <p>0000584-84-9</p> <p>2,4-TOLUENE DIISOCYANATE</p> <p>LC50 (guinea pig): 13 ppm (3-hour exposure) (11.3 ppm - equivalent 4-hour exposure) (2,4-TDI) (1) <br />LC50 (rabbit): 1.5 ppm (3-hour exposure) (1.3 ppm - equivalent 4-hour exposure) (2,4-TDI) (1) <br />LD50 (oral, rat): 5,800 mg/kg (2,4-TDI) (1) <br />LD50 (dermal, rabbit): 10,000 mg/kg (TDI, unspecified composition) (1) <br />0001333-86-4</p> <p>CARBON BLACK</p> <p>LC50 (rat): 6750 mg/m3 (4-hour exposure); cited as 27000 mg/m3 (27 mg/L) (1-hour exposure) (3)</p> <p>Acute Exposure <br />0000091-08-7</p> <p>TOLUENE-2,6-DIISOCYANATE</p> <p>It can irritate and burn the skin and eyes. Breathing can irritate the respiratory tract. Inhalation of the vapor can irritate the lungs causing <br />coughing and/or shortness of breath. Exposures can cause chemical bronchitis, pneumonitis or pulmonary edema. Exposure far above <br />the OEL could cause death.</p> <p>Chronic Exposure <br />0000091-08-7</p> <p>TOLUENE-2,6-DIISOCYANATE</p> <p>Toluene-2,6,-diisocyanate may cause a skin allergy, and may cause an asthma-like allergy. Repeated or prolonged contact may cause <br />skin sensitization. Future exposure can cause asthma attacks with shortness of breath, wheezing, cough, and/or chest tightness. <br />Repeated high exposure may cause memory and concentration problems <br />0000584-84-9</p> <p>2,4-TOLUENE DIISOCYANATE</p> <p>Animal tests in rats have shown 2,4-toluene diisocyanate to have moderate to extreme acute toxicity from inhalation exposure and low <br />acute toxicity from oral exposure. Chronic: Inhalation exposure to 2,4-toluene diisocyanate in workers has caused significant decreases <br />in lung function, an asthma-like reaction characterized by wheezing, dyspnea, and bronchial constriction. <br />0001333-86-4</p> <p>CARBON BLACK</p> <p>CARCINOGENIC EFFECTS: In 1996, the IARC reevaluated Carbon Black as a Group 2B carcinogen. This evaluation is given to <br />carbon black for which there is inadequate human evidence, but sufficient animal evidence. <br />Prolonged inhalation of Carbon black can result in lung disease. Symptoms include coughing, shortness of breath, wheezing and <br />reduced pulmonary function.</p> <p>Potential Health Effects - Miscellaneous <br />0000091-08-7</p> <p>TOLUENE-2,6-DIISOCYANATE</p> <p>Is an IARC, NTP or OSHA Carcinogen. It has been shown to cause liver cancer in animals. There is no evidence that it affects <br />reproduction. <br />0000584-84-9</p> <p>2,4-TOLUENE DIISOCYANATE</p> <p>Is an IARC, NTP or OSHA carcinogen. Exposure can result in itching of the eyes, lacrimation, and irritation of the nose and pharynx. <br />Respiratory problems that include dry cough, chest pain, difficulty in breathing, wheezing dyspnea, and respiratory distress may occur <br />later. Animal studies have reported significantly increased incidences of tumors of the pancreas, liver, and mammary glands from <br />exposure to 2,4-toluene diisocyanate via gavage. Animal studies, via inhalation, did not report an increased incidence of tumors. <br />0001333-86-4</p> <p>CARBON BLACK</p> <p>Is an IARC, NTP or OSHA carcinogen. Has shown carcinogenic activity in laboratory animals at high doses. Significance to man is <br />unknown. The following medical conditions may be aggravated by exposure: asthma, respiratory disease. WARNING: This chemical is <br />known to the State of California to cause cancer. <br />0013463-67-7</p> <p>TITANIUM DIOXIDE</p> <p>Is an IARC, NTP or OSHA carcinogen. In a lifetime inhalation test, lung cancers were found in some rats exposed to 250 mg/m3 <br />respirable titanium dust. Analysis of the titanium dioxide concentrations in the rat?s lungs showed that the lung clearance mechanism <br />was overwhelmed and that the results at the massive 250 mg/m3 level are not relevant to the workplace.?Results of a DuPont <br />epidemiology study showed that employees who had been exposed to Titanium Dioxide were at no greater risk of developing lung <br />cancer than were employees who had not been exposed to Titanium dioxide. No pulmonary fibrosis was found in any of the employees <br />and no association was observed between Titanium dioxide exposure and chronic respiratory disease or x-ray abnormalities. Based on <br />the results of this study DuPont concludes that titanium dioxide will not cause lung cancer or chronic respiratory disease in humans at <br />concentrations experienced in the workplace.?</p> <p>SDS AQUAFIN-TC125 <br />SDS DATE: 10-OCT-23</p> <p>Page 7 of 9</p> <p>0064742-95-6</p> <p>AROMATIC HYDROCARBON MIXTURE >C9</p> <p>The following medical conditions may be aggravated by exposure: skin disorders. Laboratory studies with rats have shown that <br />petroleum distillates can cause kidney damage and kidney or liver tumors. These effects were not seen in similar studies with guinea <br />pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown a significant increase of kidney damage or an <br />increase in kidney or liver tumors.</p> <p>SECTION 12) ECOLOGICAL INFORMATION <br />Toxicity: <br />No data available.</p> <p>Persistence and Degradability: <br />No data available.</p> <p>Bioaccumulative Potential: <br />No data available.</p> <p>Mobility in Soil: <br />No data available.</p> <p>Other Adverse Effects: <br />No data available.</p> <p>Bio-accumulative Potential <br />0000584-84-9</p> <p>2,4-TOLUENE DIISOCYANATE</p> <p>Not bioaccumulative (Log Pow = 3.74) <br />0001333-86-4</p> <p>CARBON BLACK</p> <p>A relevant bioaccumulation potential of carbon black is not expected based on its insolubility in organic solvents and in water. <br />Furthermore, since the aggregate diameter of carbon black varies between 80 nm and 810 nm, bioaccumulation of particulate carbon <br />black is not likely oweing to the large diameter of the solid aggregate particles.</p> <p>Mobility in Soil <br />0000584-84-9</p> <p>2,4-TOLUENE DIISOCYANATE</p> <p>Toluene diisocyanates released into the environment will tend to partition into water.</p> <p>Persistence and Degradability <br />0000584-84-9</p> <p>2,4-TOLUENE DIISOCYANATE</p> <p>Not biodegradable. <br />0001333-86-4</p> <p>CARBON BLACK</p> <p>Carbon Black's insolubility in water results in it not being biodegradable in any medium or by biota. It is considered persistent in the <br />natural environment.</p> <p>SECTION 13) DISPOSAL CONSIDERATIONS <br />Waste Disposal: <br />Under RCRA, it is the responsibility of the user of the product, to determine a the time of disposal whether the product meets RCRA criteria <br />for hazardous waste. Waste management should be in full compliance with federal, state, and local laws. <br />Empty containers retain product residue which may exhibit hazards of material, therefore do not pressurize, cut, glaze, weld or use for any <br />other purposes. Return drums to reclamation centers for proper cleaning and reuse.</p> <p>SECTION 14) TRANSPORT INFORMATION <br />U.S. DOT Information: <br />Not regulated.</p> <p>IMDG Information: <br />Shipping Name: PAINT <br />UN/NA #: 1263 <br />Hazard Class: 3 Packing Group: III <br />Placard: Flammable <br />Marine Pollutant: No data available</p> <p>IATA Information:</p> <p>SDS AQUAFIN-TC125 <br />SDS DATE: 10-OCT-23</p> <p>Page 8 of 9</p> <p>Shipping Name: PAINT <br />UN/NA #: 1263 <br />Hazard Class: 3 Packing Group: III <br />Placard: Flammable</p> <p>SECTION 15) REGULATORY INFORMATION</p> <p>CAS</p> <p>Chemical Name</p> <p>% By Weight</p> <p>Regulation List</p> <p>0000091-08-7</p> <p>TOLUENE-2,6DIISOCYANATE</p> <p>0.1% - 0.2% CERCLA,HAPS,SARA312,SARA313,VHAPS,VOC,TSCA,RCRA</p> <p>0000584-84-9</p> <p>2,4-TOLUENE <br />DIISOCYANATE</p> <p>0.1% - 0.2% CERCLA,HAPS,SARA312,SARA313,VHAPS,VOC,TSCA</p> <p>0001333-86-4</p> <p>CARBON BLACK</p> <p>0009040-80-6</p> <p>POLYURETHANE <br />PREPOLYMER</p> <p>40% - 75% SARA312,VOC,TSCA</p> <p>0013463-67-7</p> <p>TITANIUM DIOXIDE</p> <p>10% - 19% SARA312,TSCA,CA_Prop65 - California Proposition 65</p> <p>0064742-95-6</p> <p>AROMATIC <br />HYDROCARBON <br />MIXTURE >C9</p> <p>13% - 24% SARA312,VOC,TSCA</p> <p>4% - 7% SARA312,TSCA,CA_Prop65 - California Proposition 65</p> <p>SECTION 16) OTHER INFORMATION <br />OTHER INFORMATION: <br />* There are points of differences between OSHA GHS and UN GHS. In 90% of the categories, they can be used interchangeably, but for <br />the Skin Corrosion/Irritant Category and the Specific Target Organ Toxicity (Single and Repeated Exposure) Categories. In these cases, <br />our system will say UN GHS.</p> <p>GLOSSARY: <br />ACGIH- American Conference of Governmental Industrial Hygienists; ANSI- American National Standards Institute; Canadian TDGCanadian Transportation of Dangerous Goods; CAS- Chemical Abstract Service; Chemtrec- Chemical Transportation Emergency Center <br />(US); CHIP- Chemical Hazard Information and Packaging; DSL- Domestic Substances List; EC- Equivalent Concentration; EH40 (UK)HSE Guidance Note EH40 Occupational Exposure Limits; EPCRA- Emergency Planning and Community Right-To-Know Act; ESL- Effects <br />screening levels; HMIS- Hazardous Material Information Service; LC- Lethal Concentration; LD- Lethal Dose; NFPA- National Fire <br />Protection Association; OEL- Occupational Exposure Limits; OSHA- Occupational Safety and Health Administration, US Department of <br />Labor; PEL- Permissible Exposure Limit; SARA (Title III)- Superfund Amendments and Reauthorization Act; SARA 313- Superfund <br />Amendments and Reauthorization Act, Section 313; SCBA- Self-Contained Breathing Apparatus; STEL- Short Term Exposure Limit; TCEQ <br />- Texas Commission on Environmental Quality; TLV- Threshold Limit Value; TSCA- Toxic Substances Control Act Public Law 94-469; TWA <br />- Time Weighted Value; US DOT- US Department of Transportation; WHMIS- Workplace Hazardous Materials Information System.</p> <p>DISCLAIMER <br />To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries <br />assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any <br />material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain <br />hazards are described herein, we cannot guarantee that these are the only hazards that exist. The above information pertains to this product as <br />currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially <br />alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and <br />assume no liability in connection with any use of this information.</p> <p>SDS AQUAFIN-TC125 <br />SDS DATE: 10-OCT-23</p> <p>Page 9 of 9</p>
